Day 1, April 14 - Posters

Start Date

14-4-2020 9:00 AM

End Date

14-4-2020 11:00 AM

Publisher

University of Tennessee at Chattanooga

Place of Publication

Chattanooga (Tenn.)

Abstract

Our group is interested in exploiting cis-alkynyl transition metals to form trans-bidentate ligands in order to explore C—H activation. The p-cymene-supported ruthenium(II) complex (p-cym)Ru(PMe3)(C22-py)2 (where C2-2-py = 2-ethynylpyridine) has been prepared and characterized by NMR spectroscopy. We are interested in the interaction of palladium(II) acetate utilizing the Ru(II) center as a hinge in order to force the pyridine ligands to act as a trans-bidentate ligand. The synthesis and characterization of (p-cym)Ru(PMe3)(C22-py)2, reactivity with Pd(OAc)2, and comparisons to the previously reported Cp*2Ti(C2-2-py)2.

Date

4-14-2020

Document Type

posters

Language

English

Rights

http://rightsstatements.org/vocab/InC/1.0/

License

http://creativecommons.org/licenses/by/4.0/

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COinS
 
Apr 14th, 9:00 AM Apr 14th, 11:00 AM

Synthesis, characterization, and reactivity of a heterobimetallic organometallic complex with a trans bidentate ligand for catalytic carbon-hydrogen bond activation

Our group is interested in exploiting cis-alkynyl transition metals to form trans-bidentate ligands in order to explore C—H activation. The p-cymene-supported ruthenium(II) complex (p-cym)Ru(PMe3)(C22-py)2 (where C2-2-py = 2-ethynylpyridine) has been prepared and characterized by NMR spectroscopy. We are interested in the interaction of palladium(II) acetate utilizing the Ru(II) center as a hinge in order to force the pyridine ligands to act as a trans-bidentate ligand. The synthesis and characterization of (p-cym)Ru(PMe3)(C22-py)2, reactivity with Pd(OAc)2, and comparisons to the previously reported Cp*2Ti(C2-2-py)2.